Effects of vibrational excitation on the F + H2O → HF + OH reaction: dissociative photodetachment of overtone-excited [F–H

Effects of vibrational excitation on the F + H2O → HF + OH reaction: dissociative photodetachment of overtone-excited [F–H–OH]−

Published:2017 Issue:11 Volume:8 Page:7821-7833
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Ray Amelia W.¹²³⁴,Ma Jianyi⁵⁶⁷⁸,Otto Rico¹²³⁴,Li Jun⁹¹⁰¹¹⁸^ORCID,Guo Hua¹²¹³¹⁴⁴^ORCID,Continetti Robert E.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of California, San Diego

3. La Jolla

4. USA

5. Institute of Atomic and Molecular Physics

6. Sichuan University

7. Chengdu

8. China

9. School of Chemistry and Chemical Engineering

10. Chongqing University

11. Chongqing 401331

12. Department of Chemistry and Chemical Biology

13. University of New Mexico

14. Albuquerque

Abstract

Photodetaching vibrationally excited FH₂O⁻ channels energy into the reaction coordinate of the F + H₂O reaction, as shown in this joint experimental-theoretical study.

Funder

Air Force Office of Scientific Research

Basic Energy Sciences

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC03364H

Reference60 articles.

1. Some Concepts in Reaction Dynamics

2. Reaction Dynamics of Methane with F, O, Cl, and Br on ab Initio Potential Energy Surfaces

3. The Sudden Vector Projection Model for Reactivity: Mode Specificity and Bond Selectivity Made Simple

4. From ab Initio Potential Energy Surfaces to State-Resolved Reactivities: X + H2O ↔ HX + OH [X = F, Cl, and O(3P)] Reactions

5. Vibrational State Control of Bimolecular Reactions: Discovering and Directing the Chemistry

Cited by 15 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Probing the Exit Channel of the OH + CH3OH → H2O + CH3O Reaction by Photodetachment of CH3O–(H2O);The Journal of Physical Chemistry Letters;2021-12-28

2. High-Resolution Photoelectron Spectroscopy of Vibrationally Excited OH–;The Journal of Physical Chemistry A;2021-08-16

3. Dissociative photodetachment of H3O2−: a full-dimensional quantum dynamics study;Physical Chemistry Chemical Physics;2021

4. Advances and New Challenges to Bimolecular Reaction Dynamics Theory;The Journal of Physical Chemistry Letters;2020-09-24

5. Influence of Vibrational Excitation on the Reaction of F– with CH3I: Spectator Mode Behavior, Enhancement, and Suppression;The Journal of Physical Chemistry Letters;2020-05-08