Nuclearity dependent solvent contribution to the catechol oxidase activity of novel copper(ii) complexes derived from Mannich-base ligand platforms: synthesis, crystal structure and mechanism-Reference-Cited by-同舟云学术

Nuclearity dependent solvent contribution to the catechol oxidase activity of novel copper(ii) complexes derived from Mannich-base ligand platforms: synthesis, crystal structure and mechanism

Published:2017 Issue:16 Volume:41 Page:8586-8597
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Sanyal Ria¹²³⁴⁵,Ketkov Sergey⁶⁷⁸⁹⁷,Purkait Suranjana¹²³⁴,Mautner Franz A.¹⁰¹¹¹²¹³,Zhigulin Grigory⁶⁷⁸,Das Debasis¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Calcutta

3. Kolkata 700 009

4. India

5. Department of Inorganic and Physical Chemistry

6. G.A. Razuvaev Institute of Organometallic Chemistry RAS

7. 603950 Nizhny Novgorod

8. Russian Federation

9. N.I. Lobachevsky Nizhny Novgorod State University

10. Institut fuer Physikalische und Theoretische Chemie

11. Technische Universitaet Graz

12. A-8010 Graz

13. Austria

Abstract

Solvent-dependent kinetic studies of the catecholase activity of a set of Cu(ii) complexes reveal alcoholysis and hydrolysis as the governing factors for k_cat extrema.

Funder

Council of Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ00425G

Reference53 articles.

1. Multi-copper oxidases, ed. A. Messerschmidt, World Scientific, Singapore, 1997

2. Multicopper Oxidases and Oxygenases

3. Crystal structure of a plant catechol oxidase containing a dicopper center