A mononuclear, terminal titanium(<scp>iii</scp>) imido-Reference-Cited by-同舟云学术

A mononuclear, terminal titanium(iii) imido

Published:2023 Issue:67 Volume:59 Page:10101-10104
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mohar Jacob S.¹,Reinholdt Anders¹^ORCID,Keller Taylor M.¹,Carroll Patrick J.¹,Telser Joshua²^ORCID,Mindiola Daniel J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Pennsylvania, 231 S 34th Street, Philadelphia, Pennsylvania, USA

2. Department of Biological, Physical and Health Sciences, Roosevelt University, Chicago, Illinois, USA

Abstract

We report the first mononuclear TiIII complex possessing a terminal imido ligand.

Funder

University of Pennsylvania

National Science Foundation

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC01758C

Reference48 articles.

1. Generation, alkyne cycloaddition, arene carbon-hydrogen activation, nitrogen-hydrogen activation and dative ligand trapping reactions of the first monomeric imidozirconocene (Cp2Zr:NR) complexes

2. Molybdenum-mediated imido group transfer: stoichiometric and catalytic reactions and structures

3. Reactivity of Cp*W(O)2(CH2SiMe3) toward p-tolyl isocyanate: cycloaddition reactions of tungsten-oxo and -imido linkages

4. Isocyanate versus isothiocyanate insertion into alkoxo and imido ligands

5. Multiple Imido Complexes of Molybdenum: Synthesis and Reactivity of the d0 Mo(:NR)3 Functional Group

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