Highly selective transfer hydrogenation of α,β-unsaturated carbonyl compounds using Cu-based nanocatalysts

Author:

Siddqui Nazia1234,Sarkar Bipul12345ORCID,Pendem Chandrashekar1234,khatun Rubina1234,Sivakumar Konthala L. N.1234,Sasaki Takehiko678910ORCID,Bordoloi Ankur1234,Bal Rajaram1234ORCID

Affiliation:

1. Refinery Technology Division

2. CSIR-Indian Institute of Petroleum

3. Dehradun-248005

4. India

5. SKKU Advanced Institute of Nano Technology

6. Department of Complexity Science and Engineering

7. Graduate School of Frontier Sciences

8. The University of Tokyo

9. Kashiwa-shi

10. Japan

Abstract

Simultaneous dehydrogenation of cyclohexanol to cyclohexanone and hydrogenation of α,β-unsaturated carbonyl compounds to corresponding α,β-unsaturated alcohols was carried out in a single pot reaction without addition of any external hydrogen donor.

Funder

Council for Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference49 articles.

1. Metal–organic frameworks as selectivity regulators for hydrogenation reactions

2. Chemoselective Transfer Hydrogenation of α,β-Unsaturated Ketones Catalyzed by Pincer-Pd Complexes Using Alcohol as a Hydrogen Source

3. Highly Enantioselective Transfer Hydrogenation of α,β-Unsaturated Ketones

4. M. B. Smith and J.March, March's advanced organic chemistry: reactions, mechanisms, and structure, John Wiley & Sons, 2007

5. R. L. Augustine , Catalytic Hydrogenation: Techniques and Applications in Organic Synthesis, Marcel Dekker, Incorporated, 1965

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