Ring-opening of a thorium cyclopropenyl complex generates a transient thorium-bound carbene-Reference-Cited by-同舟云学术

Ring-opening of a thorium cyclopropenyl complex generates a transient thorium-bound carbene

Published:2022 Issue:48 Volume:58 Page:6805-6808
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kent Greggory T.¹,Yu Xiaojuan²^ORCID,Wu Guang¹,Autschbach Jochen²^ORCID,Hayton Trevor W.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106, USA

2. Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA

Abstract

Thermolysis of [Cp3Th(3,3-diphenylcyclopropenyl)] results in isomerization to the ring-opened product, [Cp3Th(3-phenyl-1H-inden-1-yl)] via a transient carbene intermediate.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01780F

Reference50 articles.

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2. Formation of Methane versus Benzene in the Reactions of (C 5 Me 5 ) 2 Th(CH 3 ) 2 with [CH 3 PPh 3 ]X (X=Cl, Br, I) Yielding Thorium‐Carbene or Thorium‐Ylide Complexes

3. Phosphorano-Stabilized Carbene Complexes with Short Thorium(IV)– and Uranium(IV)–Carbon Bonds

4. The U═C Double Bond: Synthesis and Study of Uranium Nucleophilic Carbene Complexes

5. Covalent Uranium Carbene Chemistry

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