From ligand exchange to reaction intermediates: what does really happen during the synthesis of emissive complexes?
Author:
Affiliation:
1. Institut für Anorganische Chemie
2. Christian-Albrechts-Universität zu Kiel
3. 24118 Kiel
4. Germany
5. DESY Photon Science
6. 22607 Hamburg
7. Department of Chemistry and Biology
8. University of Siegen
9. 57068 Siegen
Abstract
The in situ luminescence analysis of coordination sensors (ILACS) technique reveals the influence of synthesis parameters on key features of the crystallization process of [Eu(2,2′bipyridine)2(NO3)3] derivative complexes.
Funder
Deutsche Forschungsgemeinschaft
Daimler und Benz Stiftung
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP07142F
Reference37 articles.
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4. In Situ Studies on Phase Transitions of Tris(acetylacetonato)-Aluminum(III) Al(acac)3
5. Development of a new in situ analysis technique applying luminescence of local coordination sensors: principle and application for monitoring metal-ligand exchange processes
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