Insight into the deprotonation at the half-equivalence point of (thio)amido-benzimidazoles in the presence of anions
Author:
Affiliation:
1. Université de Bordeaux
2. Institut des Sciences Moléculaires UMR 5255
3. 33405 Talence
4. France
5. IECB
6. CNRS UMS 3033/INSERM US001
7. 33607 Pessac
Abstract
Three crystallographic structures highlight the acid–base half-equivalence point of hydrogen-bond donor (thio)amido-benzimidazoles induced by fluoride or benzoate salts with concomitant hydrogen-bonding and deprotonation as a merged synergic process.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB01704A
Reference42 articles.
1. What Anions Do to N−H-Containing Receptors
2. Recognition and sensing of fluoride anion
3. Advances in Anion Supramolecular Chemistry: From Recognition to Chemical Applications
4. Anion Recognition in Water: Recent Advances from a Supramolecular and Macromolecular Perspective
5. Anion Recognition and Sensing: The State of the Art and Future Perspectives
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