Solvent-induced changes in the reactivity of tricyanate esters undergoing thermal polymerization-Reference-Cited by-同舟云学术

Solvent-induced changes in the reactivity of tricyanate esters undergoing thermal polymerization

Published:2021 Issue:42 Volume:12 Page:6179-6187
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Galukhin Andrey¹^ORCID,Nikolaev Ilya¹,Nosov Roman¹,Islamov Daut²,Vyazovkin Sergey¹³^ORCID

Affiliation:

1. Alexander Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlevskaya Street, Kazan 420008, Russian Federation

2. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 8 Arbuzov, Kazan, 420088, Russian Federation

3. Department of Chemistry, University of Alabama at Birmingham, 901 S. 14th Street, Birmingham, AL 35294, USA

Abstract

The mechanism of thermally stimulated polymerization of tricyanate ester remains the same in solution as in the melt, but Arrhenius parameters of the rate-limiting reaction are significantly affected by solvation.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY01088C

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3. Continuous Solution Polymerization of Ethylene Using Metallocene Catalyst System, Zirconocene Dichloride/Methylaluminoxane/Trimethylaluminum