The molecular structure and curious motions in 1,1-difluorosilacyclopent-3-ene and silacyclopent-3-ene as determined by microwave spectroscopy and quantum chemical calculations-Reference-Cited by-同舟云学术

The molecular structure and curious motions in 1,1-difluorosilacyclopent-3-ene and silacyclopent-3-ene as determined by microwave spectroscopy and quantum chemical calculations

Published:2022 Issue:4 Volume:24 Page:2454-2464
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

McFadden Thomas M. C.¹,Moon Nicole²^ORCID,Marshall Frank E.²,Duerden Amanda J.²,Ocola Esther J.³,Laane Jaan³,Guirgis Gamil A.¹,Grubbs G. S.²^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, College of Charleston, 66 George Street, Charleston, South Carolina 29424, USA

2. Department of Chemistry, Missouri University of Science and Technology, 400 West 11th Street, Rolla, Missouri 65409, USA

3. Department of Chemistry and Institute for Quantum Science and Engineering, Texas A&M University, College Station, Texas 77843, USA

Abstract

The molecules 1,1-difluorosilacyclopent-3-ene (3SiCPF2) and silacyclopent-3-ene (3SiCP) have been synthesized and studied using chirped pulse, Fourier transform microwave (CP-FTMW) spectroscopy.

Funder

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04286F

Reference43 articles.

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