Ritter-enabled catalytic asymmetric chloroamidation of olefins-Reference-Cited by-同舟云学术

Ritter-enabled catalytic asymmetric chloroamidation of olefins

Published:2021 Issue:5 Volume:12 Page:1834-1842
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Steigerwald Daniel C.¹²³⁴,Soltanzadeh Bardia¹²³⁴,Sarkar Aritra¹²³⁴,Morgenstern Cecilia C.¹²³⁴,Staples Richard J.¹²³⁴^ORCID,Borhan Babak¹²³⁴^ORCID

Affiliation:

1. Michigan State University

2. Department of Chemistry

3. East Lansing

4. USA

Abstract

Intermolecular haloamination reactions are challenging due to the high halenium affinity of the nitrogen atom. This is circumvented by using acetonitrile as an attenuated nucleophile, resulting in an enantioselective halo-Ritter reaction.

Funder

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05224H

Reference103 articles.

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2. Stereoselective Halogenation in Natural Product Synthesis

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4. Recent Progress in the Asymmetric Intermolecular Halogenation of Alkenes

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