Crystal structure and properties of perovskite-type rubidium niobate, a high-pressure phase of RbNbO3

Author:

Yamamoto Ayako1ORCID,Murase Kimitoshi1,Sato Takeru1,Sugiyama Kazumasa2,Kawamata Toru2,Inaguma Yoshiyuki3ORCID,Yamaura Jun-ichi4ORCID,Shitara Kazuki5ORCID,Yokoi Rie5,Moriwake Hiroki56ORCID

Affiliation:

1. Graduate School of Engineering and Science, Shibaura Institute of Technology, 307 Fukasaku, Minuma, Saitama, 337-8570, Japan

2. Institute for Materials Research, Tohoku University, 2-1 Katahira, Aoba, Sendai, 980, Japan

3. Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan

4. Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba, 277-8581, Japan

5. Nanostructures Research Laboratory, Japan Fine Ceramics Center, 2-4-1 Mutsuno, Atsuta, Nagoya, 456-8587, Japan

6. International Research Frontiers Initiative (IRFI), MDX Research Center for Element Strategy (MDXES), Tokyo Institute of Technology, SE-6, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa, 226-8501 Japan

Abstract

Towards new ferroelectrics design, we investigated crystal structure and properties of perovskite-RbNbO3 prepared at 4 GPa. Single-crystal XRD analysis revealed RbNbO3 exhibits the same non-centrosymmetric SG(Amm2) as ferroelectrics BaTiO3 and KNbO3.

Funder

Kazuchika Okura Memorial Foundation

Institute for Materials Research, Tohoku University

Publisher

Royal Society of Chemistry (RSC)

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