Snowflake relocated Cu2O electrocatalyst on an Ag backbone template for the production of liquid C2+ chemicals from CO2

Author:

Lee Youjin123ORCID,Choi Minjun123ORCID,Bae Sooan123ORCID,Tayal Akhil4,Seo Okkyun5,Lim Hojoon4ORCID,Lee Kug-Seung6ORCID,Jang Jae Hyuck7,Jeong Beomgyun8,Lee Jaeyoung123ORCID

Affiliation:

1. School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdangwagi-Ro, Buk-gu, Gwangju 61005, Republic of Korea

2. International Future Research Center of Chemical Energy Storage and Conversion Processes (ifRC-CHESS), GIST, 123 Cheomdangwagi-Ro, Buk-gu, Gwangju 61005, Republic of Korea

3. Ertl Center for Electrochemistry and Catalysis, GIST, 123 Cheomdangwagi-Ro, Buk-gu, Gwangju 61005, Republic of Korea

4. National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, New York 11973, USA

5. Center for Synchrotron Radiation Research, Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo, Hyogo 679-5198, Japan

6. Pohang Accelerator Laboratory, Pohang University of Science and Technology, Pohang 37673, Republic of Korea

7. Center for Research Equipment, Korea Basic Science Institute (KBSI), 169-148 Gwahak-ro, Yuseong-gu, Daejeon 34133, Republic of Korea

8. Research Center for Materials Analysis, KBSI, 169-148 Gwahak-ro, Yuseong-gu, Daejeon 34133, Republic of Korea

Abstract

Cu2O–Ag exhibits a great performance in producing liquid C2+ products since the larger interface of the relocated Cu(111)–Ag results in more active sites to proceed with the C–C coupling reaction that prohibits the ethylene pathway.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

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