Stepwise approach for sterically hindered Csp3–Csp3 bond formation by dehydrogenative O-alkylation and Lewis acid-catalyzed [1,3]-rearrangement towards the arylalkylcyclopentane skeleton of sesquiterpenes-Reference-Cited by-同舟云学术

Stepwise approach for sterically hindered Csp3–Csp3 bond formation by dehydrogenative O-alkylation and Lewis acid-catalyzed [1,3]-rearrangement towards the arylalkylcyclopentane skeleton of sesquiterpenes

Published:2020 Issue:25 Volume:56 Page:3621-3624
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fujitani Ban¹²³⁴⁵,Hanaya Kengo¹²³⁴⁵,Sugai Takeshi¹²³⁴⁵^ORCID,Higashibayashi Shuhei¹²³⁴⁵^ORCID

Affiliation:

1. Department of Pharmaceutical Sciences

2. Faculty of Pharmacy

3. Keio University

4. Tokyo 105-8512

5. Japan

Abstract

A stepwise dehydrogenative cross-coupling method was developed for the formation of sterically hindered C_sp3–C_sp3 bonds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01017K

Reference32 articles.

1. The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

2. Metal-Free Oxidative CC Bond Formation through CH Bond Functionalization

3. Coordinating activation strategy for C(sp3)–H/C(sp3)–H cross-coupling to access β-aromatic α-amino acids

4. Manganese/cobalt-catalyzed oxidative C(sp3)–H/C(sp3)–H coupling: a route to α-tertiary β-arylethylamines

5. Chemoselective Catalytic Dehydrogenative Cross-Coupling of 2-Acylimidazoles: Mechanistic Investigations and Synthetic Scope

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