Organopnictogen(<scp>iii</scp>) bis(arylthiolates) containing NCN-aryl pincer ligands: from synthesis and characterization to reactivity-Reference-Cited by-同舟云学术

Organopnictogen(iii) bis(arylthiolates) containing NCN-aryl pincer ligands: from synthesis and characterization to reactivity

Published:2022 Issue:27 Volume:51 Page:10406-10419
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Duneş Gabriel¹^ORCID,Soran Albert¹^ORCID,Silvestru Cristian¹^ORCID

Affiliation:

1. Department of Chemistry, Supramolecular Organic and Organometallic Chemistry Centre (SOOMCC), Faculty of Chemistry and Chemical Engineering, Babeş-Bolyai University, 11 Arany Janos, 400028 Cluj-Napoca, Romania

Abstract

A family of new hypercoordinated organopnictogen(iii) di(thiolates), RPn(SC6H3Me2-2,6)2 (Pn = Sb, Bi; R = NCN-pincer ligand), has been prepared and their reactivity towards chalcogens and iodine has been investigated.

Funder

Ministerul Cercetării şi Inovării

Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01436J

Reference93 articles.

1. The chemistry of Group 13/15 compounds (III–V compounds) with the higher homologues of Group 15, Sb and Bi

2. Covalently bonded compounds of heavy group 15/16 elements – Synthesis, structure and potential application in material sciences