From a one-mode to a multi-mode understanding of conical intersection mediated ultrafast organic photochemical reactions-Reference-Cited by-同舟云学术

From a one-mode to a multi-mode understanding of conical intersection mediated ultrafast organic photochemical reactions

Published:2023 Issue:8 Volume:52 Page:2643-2687
ISSN:0306-0012
Container-title:Chemical Society Reviews
language:en
Short-container-title:Chem. Soc. Rev.

Author:

Boeije Yorrick¹^ORCID,Olivucci Massimo²³^ORCID

Affiliation:

1. Van 't Hoff Institute for Molecular Sciences (HIMS), University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

2. Chemistry Department, University of Siena, Via Aldo Moro n. 2, 53100 Siena, Italy

3. Chemistry Department, Bowling Green State University, Overman Hall, Bowling Green, Ohio 43403, USA

Abstract

This review discusses how ultrafast organic photochemical reactions are controlled by conical intersections, highlighting that decay to the ground-state at multiple points of the intersection space results in their multi-mode character.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CS/D2CS00719C

Reference340 articles.

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2. The non-crossing rule in molecular quantum mechanics

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4. Intersection of potential energy surfaces in polyatomic molecules

5. Non-adiabaticity: the importance of conical intersections

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