NHC induced radical formation <i>via</i> homolytic cleavage of B–B bonds and its role in organic reactions-Reference-Cited by-同舟云学术

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NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions

Published:2022 Issue:28 Volume:13 Page:8321-8333
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kuehn Laura¹,Zapf Ludwig¹,Werner Luis¹,Stang Martin¹^ORCID,Würtemberger-Pietsch Sabrina¹,Krummenacher Ivo¹,Braunschweig Holger¹^ORCID,Lacôte Emmanuel²^ORCID,Marder Todd B.¹^ORCID,Radius Udo¹^ORCID

Affiliation:

1. Institute for Inorganic Chemistry, Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

2. Univ Lyon, Université Claude Bernard Lyon 1, CNRS, CNES, ArianeGroup, LHCEP, Bât. Raulin, 2 rue Victor Grignard, F-69622 Villeurbanne, France

Abstract

Bis-NHC adducts of the type (NHC)2·B2(OR)4 are sources of boryl radicals of the type NHC–BR2˙, which are formed by homolytic B–B bond cleavage.

Funder

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02096C

Reference121 articles.

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2. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

3. The Palladium-Catalyzed Cross-Coupling Reaction of Phenylboronic Acid with Haloarenes in the Presence of Bases

4. Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds

5. A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

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