Supported sub-nanometer Ta oxide clusters as model catalysts for the selective epoxidation of cyclooctene-Reference-Cited by-同舟云学术

Supported sub-nanometer Ta oxide clusters as model catalysts for the selective epoxidation of cyclooctene

Published:2018 Issue:4 Volume:42 Page:3035-3041
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Zwaschka G.¹²³⁴⁵,Rondelli M.¹²³⁴⁵,Krause M.¹²³⁴⁵,Rötzer M. D.¹²³⁴⁵,Hedhili M. N.⁶⁷⁸⁹,Heiz U.¹²³⁴⁵,Basset J.-M.⁶¹⁰⁸⁹^ORCID,Schweinberger F. F.¹²³⁴⁵^ORCID,D'Elia V.⁶¹⁰⁸⁹¹¹^ORCID

Affiliation:

1. Technical University of Munich

2. Catalysis Research Center and Chemistry Department

3. Chair of Physical Chemistry

4. 85748 Garching

5. Germany

6. King Abdullah University of Science and Technology (KAUST)

7. Imaging and Characterization Core Lab

8. Thuwal 23955-6900

9. Kingdom of Saudi Arabia

10. Kaust Catalysis Center (KCC)

11. Vidyasirimedhi Institute of Science and Technology (VISTEC)

Abstract

The preparation of organic ligand-free, isolated and catalytically active tantalum oxide complexes (Ta₁) and small clusters (Ta_n>1) on flat silicate support was accomplished by ultra-high vacuum (UHV) techniques followed by oxidation in air.

Funder

Deutsche Forschungsgemeinschaft

Thailand Research Fund

Global Collaborative Research, King Abdullah University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ04275B

Reference53 articles.

1. Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry