Interplay between coordination sphere engineering and properties of nickel diketonate–diamine complexes as vapor phase precursors for the growth of NiO thin films

Author:

Benedet Mattia12,Barreca Davide2ORCID,Fois Ettore3ORCID,Seraglia Roberta2,Tabacchi Gloria3ORCID,Roverso Marco12ORCID,Pagot Gioele4ORCID,Invernizzi Cristiano3ORCID,Gasparotto Alberto12ORCID,Heidecker Alexandra A.5,Pöthig Alexander5ORCID,Callone Emanuela6ORCID,Dirè Sandra6,Bogialli Sara12ORCID,Di Noto Vito4ORCID,Maccato Chiara12ORCID

Affiliation:

1. Department of Chemical Sciences – Padova University and INSTM, Via Marzolo 1, 35131 Padova, Italy

2. CNR-ICMATE and INSTM – Department of Chemical Sciences – Padova University, Via Marzolo 1, and Corso Stati Uniti 4, 35127 Padova, Italy

3. Department of Science and High Technology – Insubria University and INSTM, Via Valleggio 11, 22100 Como, Italy

4. Section of Chemistry for the Technology (ChemTech), Department of Industrial Engineering – Padova University and INSTM, Via Marzolo 9, 35131 Padova, Italy

5. Catalysis Research Center & Department of Chemistry – Technische Universität München, Lichtenbergstr. 4, 85747 Garching, Germany

6. “Klaus Müller” Magnetic Resonance Laboratory, Department of Industrial Engineering – Trento University, Via Sommarive 9, 38123 Trento, Italy

Abstract

Coordination sphere engineering of nickel diketonate–diamine adducts enables tailoring of precursor properties of relevance for the vapor phase deposition of pure NiO films.

Funder

Consiglio Nazionale delle Ricerche

Università degli Studi di Padova

Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali

Università degli Studi dell'Insubria

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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