Probing the role of surface termination in the adsorption of azupyrene on copper

Author:

Klein Benedikt P.12,Stoodley Matthew A.12ORCID,Morgan Dylan B.2ORCID,Rochford Luke A.1,Williams Leon B. S.134,Ryan Paul T. P.15,Sattler Lars6,Weber Sebastian M.6,Hilt Gerhard6,Liddy Thomas J.17,Lee Tien-Lin1,Maurer Reinhard J.28ORCID,Duncan David A.1ORCID

Affiliation:

1. Diamond Light Source, Harwell Science and Innovation Campus, Didcot, OX11 0DE, UK

2. Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK

3. School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK

4. School of Physics and Astronomy, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK

5. Department of Materials, Imperial College London, Prince Consort Rd, SW7 2AZ, UK

6. Institut für Chemie, Carl von Ossietzky Universität Oldenburg, Carl-von-Ossietzky-Straße 9-11, 26111 Oldenburg, Germany

7. School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK

8. Department of Physics, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK

Abstract

Quantitative study into how the adsorption of aromatic molecules is affected by surface termination in the absence of clear directional bonds to the substrate. Subtle differences are found between the studied terminations as shown by X-ray standing waves and density functional theory.

Funder

Diamond Light Source

Deutsche Forschungsgemeinschaft

Engineering and Physical Sciences Research Council

University of Nottingham

UK Research and Innovation

Publisher

Royal Society of Chemistry (RSC)

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