Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation-Reference-Cited by-同舟云学术

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Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation

Published:2020 Issue:16 Volume:11 Page:4138-4149
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Messelberger Julian¹²³⁴,Grünwald Annette¹²³⁴,Goodner Stephen J.¹²³⁴,Zeilinger Florian¹²³⁴,Pinter Piermaria¹²³⁴,Miehlich Matthias E.¹²³⁴,Heinemann Frank W.¹²³⁴,Hansmann Max M.⁵⁶⁷⁴⁸^ORCID,Munz Dominik¹²³⁴^ORCID

Affiliation:

1. Lehrstuhl für Allgemeine und Anorganische Chemie

2. Friedrich-Alexander-Universität Erlangen-Nürnberg

3. 91058 Erlangen

4. Germany

5. Institut für Organische und Biomolekulare Chemie

6. Georg-August Universität Göttingen

7. 37077 Göttingen

8. Organische Chemie

Abstract

Only sterics and aromaticity control whether radical olefin cations are stable.

Funder

Boehringer Ingelheim Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC00699H

Reference130 articles.

1. Reactions of Electron-Rich Olefins

2. Reactions of Electron-Rich Olefins with Proton-Active Compounds

3. The coordination chemistry of electron-rich alkenes (enetetramines)

4. Organic Electron Donors as Powerful Single-Electron Reducing Agents in Organic Synthesis

5. Discovery and Development of Organic Super-Electron-Donors

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