Site-selective benzylic C–H hydroxylation in electron-deficient azaheterocycles-Reference-Cited by-同舟云学术

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Site-selective benzylic C–H hydroxylation in electron-deficient azaheterocycles

Published:2024 Issue:24 Volume:22 Page:4888-4894
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kaur Milanpreet¹,Cooper Julian C.²,Van Humbeck Jeffrey F.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N 1N4, Canada

2. Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL, 61801, USA

Abstract

This report describes the use of iodine(III) to site-selectively hydroxylate adjacent to electron-deficient heterocycles such as pyridine and pyrimidine.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

University of Calgary

Massachusetts Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00268G

Reference67 articles.

1. Selective functionalization of benzylic C(sp3)–H bonds to synthesize complex molecules

2. Copper-Catalyzed Benzylic C–H Cross-Coupling Enabled by Redox Buffers: Expanding Synthetic Access to Three-Dimensional Chemical Space

3. Photochemical and Electrochemical Strategies towards Benzylic C−H Functionalization: A Recent Update

4. Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds

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