Valence tautomerism in a [2 × 2] Co4 grid complex containing a ditopic arylazo ligand

Author:

Bonanno Nico M.1234,Watts Zackery1234,Mauws Cole1564ORCID,Patrick Brian O.1784,Wiebe Christopher R.15641ORCID,Shibano Yuki910111213,Sugisaki Kenji910111213ORCID,Matsuoka Hideto910111213ORCID,Shiomi Daisuke910111213ORCID,Sato Kazunobu910111213ORCID,Takui Takeji910111213ORCID,Lemaire Martin T.1234ORCID

Affiliation:

1. Department of Chemistry

2. Brock University

3. St. Catharines

4. Canada

5. University of Manitoba

6. Winnipeg

7. University of British of Columbia

8. Vancouver

9. Department of Chemistry and Molecular Materials Science

10. Graduate School of Science

11. Osaka City University

12. Osaka 558 8585

13. Japan

Abstract

A [2 × 2] cobalt grid complex containing a ditopic arylazo trianion-radical ligand is shown to exhibit valence tautomerism in the solid state.

Funder

Natural Sciences and Engineering Research Council of Canada

Japan Society for the Promotion of Science

Canada Foundation for Innovation

Canada Research Chairs

Air Force Office of Scientific Research

Brock University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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