Effect of the grafting agent on the structure and catalytic performance of Ti-MCM-22-Reference-Cited by-同舟云学术

Effect of the grafting agent on the structure and catalytic performance of Ti-MCM-22

Published:2016 Issue:20 Volume:6 Page:7631-7642
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Chang Chih-Cheng¹²³⁴,Jin Fang⁵⁶⁷⁸⁹,Jang Ling-Yun¹⁰¹¹¹²⁴,Lee Jyh-Fu¹⁰¹¹¹²⁴,Cheng Soofin¹²³⁴

Affiliation:

1. Department of Chemistry

2. National Taiwan University

3. Taipei 106

4. Taiwan

5. Key Laboratory for Green Chemical Process of Ministry of Education

6. School of Chemical and Pharmaceutical Engineering

7. Wuhan Institute of Technology

8. Wuhan 430073

9. China

10. Research Division

11. National Synchrotron Radiation Research Center

12. Hsinchu 300

Abstract

Ti-MCM-22 prepared by grafting with Ti(OEt)₄ has more Ti(iv) at Td sites than those prepared with Ti(OPr)₄ and Ti(OBu)₄, and gives higher catalytic activities in cyclohexene and cyclooctene epoxidation using t-butylhydrogen peroxide as the oxidant.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C6CY01591C

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4. A Novel Titanosilicate with MWW Structure: II. Catalytic Properties in the Selective Oxidation of Alkenes

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