Trinuclear alkyl hydrido rare-earth complexes supported by amidopyridinato ligands: synthesis, structures, C–Si bond activation and catalytic activity in ethylene polymerization-Reference-Cited by-同舟云学术

Trinuclear alkyl hydrido rare-earth complexes supported by amidopyridinato ligands: synthesis, structures, C–Si bond activation and catalytic activity in ethylene polymerization

Published:2014 Issue:38 Volume:43 Page:14450-14460
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Lyubov Dmitry M.¹²³²,Cherkasov Anton V.¹²³²,Fukin Georgy K.¹²³²,Ketkov Sergey Yu.¹²³²,Shavyrin Andrey S.¹²,Trifonov Alexander A.¹²³²⁴

Affiliation:

1. G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences

2. Nizhny Novgorod, Russia

3. Nizhny Novgorod State University

4. A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences

Abstract

[(Ap^9MeLu)₃(μ²-H)₃(μ³-H)₂(CH₂SiMe₃)(thf)₂] was synthesized. For Y and Yb C–Si bond activation occurs affording [(Ap^9MeLu)₃(μ²-H)₃(μ³-H)₂(CH₂SiMe₃)(thf)₂] and [(Ap^9MeLn)₃(μ²-H)₃(μ³-H)₂(CH₂SiH₂Ph)(thf)₂].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00806E

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