Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP]3+/[LPF2]3+ redox couple-Reference-Cited by-同舟云学术

Tris(benzoimidazol)amine (L) complexes of pnictogen(iii) and pnictogen(v) cations and assessment of the [LP]3+/[LPF2]3+ redox couple

Published:2018 Issue:26 Volume:9 Page:5837-5841
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Swidan Ala'aeddeen¹²³⁴^ORCID,Suter Riccardo⁵⁶⁷⁴^ORCID,Macdonald Charles L. B.¹²³⁴^ORCID,Burford Neil⁵⁶⁷⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Windsor

3. Windsor

4. Canada

5. Department of Chemistry

6. University of Victoria

7. Victoria

Abstract

A tris((1-ethyl-benzoimidazol-2-yl)methyl)amine (BIMEt₃) complex of P³⁺ is oxidized with XeF₂ to access [PF₂(BIMEt₃)]³⁺ representing the first structurally characterized example of a phosphorus(v)³⁺ cation.

Funder

Natural Sciences and Engineering Research Council of Canada

University of Victoria

University of Windsor

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01682H

Reference41 articles.

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3. Stable singlet carbenes as mimics for transition metal centers

4. Intermolecular N–H Oxidative Addition of Ammonia, Alkylamines, and Arylamines to a Planar σ3-Phosphorus Compound via an Entropy-Controlled Electrophilic Mechanism

5. Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

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