Stepwise deprotonation of truxene: structures, metal complexation, and charge-dependent optical properties-Reference-Cited by-同舟云学术

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Stepwise deprotonation of truxene: structures, metal complexation, and charge-dependent optical properties

Published:2023 Issue:45 Volume:14 Page:13219-13227
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guo Yumeng¹^ORCID,Torchon Herdya S.²^ORCID,Zhu Yikun²^ORCID,Wei Zheng²^ORCID,Zhang Zhenyi³^ORCID,Han Haixiang¹,Petrukhina Marina A.²^ORCID,Zhou Zheng¹^ORCID

Affiliation:

1. School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

2. Department of Chemistry, University at Albany, State University of New York, Albany, NY 12222, USA

3. Bruker (Beijing) Scientific Technology Co., Ltd, Shanghai 200233, China

Abstract

Stepwise deprotonation of truxene with alkali metals affords truxenyl anions with different charges, exhibiting core curvature dependence on charge and metal binding. UV-vis and PL studies reveal charge-dependent optical properties, which is further supported by DFT calculations.

Funder

National Natural Science Foundation of China

National Science Foundation

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC04885C

Reference50 articles.

1. C60: Buckminsterfullerene

2. Toward Negatively Curved Carbons

3. Polycyclic aromatic hydrocarbons in the graphene era

4. Bowls, Hoops, and Saddles: Synthetic Approaches to Curved Aromatic Molecules

5. Aromatic hydrocarbon belts

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