Temperature dependence of desolvation effects in hydrogen-bonded spin crossover complexes

Author:

Jornet-Mollá Verónica1234ORCID,Giménez-Saiz Carlos1234ORCID,Vieira Bruno J. C.56789ORCID,Waerenborgh João C.56789ORCID,Romero Francisco M.1234ORCID

Affiliation:

1. Instituto de Ciencia Molecular (ICMol)

2. Universidad de Valencia

3. 46980 Paterna

4. Spain

5. Centro de Ciências e Tecnologias Nucleares (C2TN)

6. Instituto Superior Técnico

7. Universidade de Lisboa

8. 2695-066 Bobadela LRS

9. Portugal

Abstract

Dehydration temperature influences the crystallinity and spin crossover properties of a hydrogen-bonded iron(ii) salt containing flexible dicarboxylate anions.

Funder

Generalitat Valenciana

Secretaría de Estado de Investigación, Desarrollo e Innovación

Ministerio de Ciencia e Innovación

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference50 articles.

1. Spin Crossover in Transition Metal Compounds , in Topics in Current Chemistry , ed. P. Gütlich and H. A. Goodwin , Springer Verlag , Berlin-Heidelberg-New York , 2004 , vol. 233–235

2. Spin-Crossover Materials: Properties and Applications , ed. M. A. Halcrow , John Wiley & Sons , Chichester, UK , 2013

3. Spin state switching in iron coordination compounds

4. Spin-crossover compounds based on iron(ii) complexes of 2,6-bis(pyrazol-1-yl)pyridine (bpp) functionalized with carboxylic acid and ethyl carboxylic acid

5. Very Long-Lived Photogenerated High-Spin Phase of a Multistable Spin-Crossover Molecular Material

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