Uphill diffusion in multicomponent mixtures-Reference-Cited by-同舟云学术

Uphill diffusion in multicomponent mixtures

Published:2015 Issue:10 Volume:44 Page:2812-2836
ISSN:0306-0012
Container-title:Chemical Society Reviews
language:en
Short-container-title:Chem. Soc. Rev.

Author:

Krishna Rajamani¹²³⁴

Affiliation:

1. Van't Hoff Institute for Molecular Sciences

2. University of Amsterdam

3. 1098 XH Amsterdam

4. The Netherlands

Abstract

Diffusional coupling effects may cause uphill transport of a species against its concentration gradient. Transient overshoots and serpentine equilibration trajectories in composition space are fingerprints of uphill diffusion. Serpentine diffusion trajectories may enter meta-stable zones, leading to spontaneous emulsification and the Ouzo effect.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CS/C4CS00440J

Reference50 articles.

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3. D. M. Ruthven , S.Farooq and K. S.Knaebel, Pressure swing adsorption, VCH Publishers, New York, 1994

4. R. Taylor and R.Krishna, Multicomponent mass transfer, John Wiley, New York, 1993

5. An experimental study of three component gas diffusion

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