Stereo-controlled cyclopropanation catalysis within the confined pores of porphyrin MOFs-Reference-Cited by-同舟云学术

Stereo-controlled cyclopropanation catalysis within the confined pores of porphyrin MOFs

Published:2023 Issue:11 Volume:13 Page:3304-3312
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Hemmer Karina¹^ORCID,Bühler Raphael¹,Elsner Martin²^ORCID,Cokoja Mirza¹^ORCID,Fischer Roland A.¹^ORCID

Affiliation:

1. Technical University of Munich, School of Natural Sciences, Department of Chemistry, and Catalysis Research Center (CRC), Chair of Inorganic and Metal-Organic Chemistry, Ernst-Otto-Fischer-Strasse 1, D-85748 Garching bei München, Germany

2. Technical University of Munich, School of Natural Sciences, Department of Chemistry, Chair of Analytical Chemistry and Water Chemistry, Lichtenbergstrasse 4, D-85748 Garching bei München, Germany

Abstract

Three Rh-porphyrin MOF catalysts show a MOF topology independent stereoselectivity enhancement for styrene derivatives with coordinating functionalities. Upon donor molecule addition, the activity is increased facilitating Rh-carbene formation.

Funder

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D2CY02144G

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