Influence of Mo doping on interfacial charge carrier dynamics in photoelectrochemical water oxidation on BiVO4

Author:

Wu Xiaofeng1ORCID,Oropeza Freddy E.2ORCID,Qi Zheng3,Einert Marcus1ORCID,Tian Chuanmu1ORCID,Maheu Clément1ORCID,Lv Kangle3ORCID,Hofmann Jan P.1ORCID

Affiliation:

1. Surface Science Laboratory, Department of Materials and Earth Sciences, Technical University of Darmstadt, Otto-Berndt-Strasse 3, 64287 Darmstadt, Germany

2. Photoactivated Processes Unit, IMDEA Energy Institute, Parque Tecnológico de Móstoles, Avda. Ramón de la Sagra 3, 28935 Móstoles, Madrid, Spain

3. Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, College of Resources and Environment, South-Central Minzu University, Wuhan 430074, China

Abstract

Intensity of photocurrent during water oxidation in BiVO4 is predominantly limited by charge transfer resistance (Rct), rather than semiconductor bulk resistance (Rbulk). Mo doping of BiVO4 can slightly reduce Rbulk but obviously decreases Rct.

Funder

Deutsche Forschungsgemeinschaft

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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