Affiliation:
1. Institute of Chemical Research of Catalonia (ICIQ-CERCA), The Barcelona Institute of Science and Technology (BIST), Avgda. Països Catalans 16, 43007, Tarragona, Spain
2. ICREA, Passeig Lluís Companys, 23, 08018 Barcelona, Spain
Abstract
The “Circe effect” in supramolecular catalysis: the investment in entropy of CB[7] upon substrate binding accounts for the acceleration (kincluded/kbulk up to 104!) of the intramolecular Diels–Alder reaction of tertiary furfuryl amines.
Funder
Agència de Gestió d'Ajuts Universitaris i de Recerca
Ministerio de Ciencia, Innovación y Universidades
Agencia Estatal de Investigación
Centres de Recerca de Catalunya
Institut Català d'Investigació Química
Horizon 2020 Framework Programme
Publisher
Royal Society of Chemistry (RSC)
Cited by
2 articles.
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