Persistent arsenate–iron(iii) oxyhydroxide–organic matter nanoaggregates observed in coal

Author:

Zhang Yinfeng12ORCID,Li Shehong2ORCID,Sun Jing2ORCID,Bostick Benjamin C.3ORCID,Zheng Yan45ORCID

Affiliation:

1. Yunnan Key Laboratory of Plateau Wetland Conservation, Restoration and Ecological Services, College of Wetlands, Southwest Forestry University, Kunming, 650224, China

2. State Key Lab of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550081, China

3. Lamont-Doherty Earth Observatory, Columbia University, 61 Route 9W, Palisades, NY 10964, USA

4. State Environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution Control, School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen, 518055, China

5. Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen, 518055, China

Abstract

Synchrotron X-ray absorption spectroscopy analysis of high arsenic Guizhou coal samples reveals stable nano-aggregates of As(v) bound through edge-sharing with Fe(iii)-oxyhydroxide within an organic matter matrix.

Funder

National Natural Science Foundation of China

National Science Foundation

National Institute of Environmental Health Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Environmental Science,Materials Science (miscellaneous)

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