Structural chemistry of penta- and hexanitrato thorium(<scp>iv</scp>) complexes isolated using N

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Structural chemistry of penta- and hexanitrato thorium(iv) complexes isolated using N–H donors

Published:2024 Issue:10 Volume:26 Page:1380-1398
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Shore Madeline C.¹^ORCID,Nicholas Aaron D.²^ORCID,Vasiliu Monica³^ORCID,Edwards Kyle C.³,de Melo Gabriel F.³,Bertke Jeffery A.¹^ORCID,Dixon David A.³^ORCID,Knope Karah E.¹^ORCID

Affiliation:

1. Department of Chemistry, Georgetown University, Washington, D.C. 20057, USA

2. Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA, 99354, USA

3. Department of Chemistry and Biochemistry, The University of Alabama, Tuscaloosa, Alabama 35487, USA

Abstract

Fifteen Th(iv)–nitrate compounds, consisting of [Th(NO3)5(H2O)2]1− or [Th(NO3)6]2− units, were isolated from aqueous solution using a series of N–H heterocycles.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D3CE01319G

Reference64 articles.

1. Elucidating Actinide–Pertechnetate and Actinide–Perrhenate Bonding via a Family of Th–TcO₄ and Th–ReO₄ Frameworks and Solutions

2. Actinide Environmental Chemistry

3. Environmental Speciation of Actinides

4. Redox and environmentally relevant aspects of actinide(IV) coordination chemistry

5. Solution Thermodynamics and Kinetics of Metal Complexation with a Hydroxypyridinone Chelator Designed for Thorium-227 Targeted Alpha Therapy

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