Microcalorimetric adsorption and infrared spectroscopic studies of supported Pd, Ru and Pd–Ru catalysts for the hydrogenation of aromatic rings with carboxyl groups

Author:

Zhao Shiling12345,Cai Jingxuan12345,Hou Qiumei12345,Zhao Danyang12345,Shen Jianyi12345ORCID

Affiliation:

1. Laboratory of Mesoscopic Chemistry

2. School of Chemistry and Chemical Engineering

3. Nanjing University

4. Nanjing 210023

5. PR China

Abstract

Pd–Ru/SiO2 showed special surface chemical properties that were totally different from those of Pd/SiO2 and Ru/SiO2 and exhibited high activity and selectivity for the hydrogenation of benzoic acid to cyclohexanecarboxylic acid.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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