Rh(i) and Ru(ii) phosphaamidine and phosphaguanidine (1,3-P,N) complexes and their activity for CO2 hydrogenation
Author:
Affiliation:
1. Department of Chemistry
2. Queen's University
3. Kingston
4. Canada
Abstract
Phosphaamidine and phosphaguanidine complexes Rh2Cl2L2(μ-CO), RuCl2L2, [RhL′(COD)]BF4, RuCl2L′(DMSO)2 and RuCl2L′′(DMSO)2 (L = Ph2PC(Ph)NPh, L′ = [iPr2PC(Ph)NiPr, L′′ = Me2NC(PPh2)NiPr) are shown to be precatalysts for CO2 hydrogenation.
Funder
Natural Sciences and Engineering Research Council of Canada
Canada Research Chairs
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00602H
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