Lewis acid capping of a uranium(v) nitride via a uranium(iii) azide molecular square-Reference-Cited by-同舟云学术

Lewis acid capping of a uranium(v) nitride via a uranium(iii) azide molecular square

Published:2020 Issue:33 Volume:56 Page:4535-4538
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Boreen Michael A.¹²³⁴⁵^ORCID,Rao Guodong¹²⁶⁴^ORCID,Villarreal David G.¹²⁶⁴^ORCID,Watt Fabian A.⁷⁸⁹,Britt R. David¹²⁶⁴^ORCID,Hohloch Stephan¹⁰¹¹¹²¹³¹⁴^ORCID,Arnold John¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of California

3. Berkeley

4. USA

5. Chemical Sciences Division

6. Davis

7. Paderborn University

8. 33098 Paderborn

9. Germany

10. Leopold-Franzens-University Innsbruck

11. Faculty of Chemistry and Pharmacy

12. Institute of General

13. Inorganic and Theoretical Chemistry

14. 6020 Innsbruck

Abstract

Addition of B(C₆F₅)₃ to a tetrameric uranium(iii) azide-bridged molecular square induced N₂ loss and formation of a uranium(v) borane-capped nitride.

Funder

U.S. Department of Energy

National Science Foundation

Universität Innsbruck

Universität Paderborn

Verband der Chemischen Industrie

Daimler und Benz Stiftung

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01356K

Reference50 articles.

1. Progress in molecular uranium-nitride chemistry

2. M. A. Boreen and J.Arnold , Multiple Bonding in Actinide Chemistry , in Encyclopedia of Inorganic and Bioinorganic Chemistry , ed. R. A. Scott , Wiley , Hoboken , 2018 10.1002/9781119951438.eibc2535

3. Recent developments in actinide–ligand multiple bonding

4. Nitride layers on uranium surfaces

5. Accident tolerant fuels for LWRs: A perspective

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