Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)-Reference-Cited by-同舟云学术

Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)

Published:2021 Issue:34 Volume:50 Page:12006-12015
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Kewang¹,Huang Junben²^ORCID,Chen Zhikang¹,Zhang Bei¹,Lee Ming-Hsien³,Zhang Jun¹^ORCID

Affiliation:

1. School of Physics Science and Technology, Xinjiang University, Urumqi 830046, Xinjiang, People's Republic of China

2. School of Materials Science and Engineering, Education Ministry Key Laboratory of Non-ferrous Materials Science and Engineering, Central South University, Changsha 410083, Hunan, China

3. Department of Physics, Tamkang University, New Taipei 25137, Taiwan

Abstract

Halogens modulating the polarizability anisotropy of the polyhedra caused a large birefringence changes (about 8 times) in α/β-Cd2P3X (X = Cl to I) by the synergistic effect of anion size and covalent interactions between halogens and metal cations.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01168E

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