A new strategy for hyperconjugative antiaromatic compounds utilizing negative charges: a dibenzo[b,f]silepinyl dianion-Reference-Cited by-同舟云学术

A new strategy for hyperconjugative antiaromatic compounds utilizing negative charges: a dibenzo[b,f]silepinyl dianion

Published:2021 Issue:86 Volume:57 Page:11330-11333
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ito Shotaro¹,Ishii Youichi¹^ORCID,Ishimura Kazuya²^ORCID,Kuwabara Takuya³^ORCID

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo, 112-8551, Japan

2. X-Ability, Co., Ltd., Ishiwata Building 3rd Floor, 4-1-5 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan

3. Department of Chemistry and Biochemistry, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1, Otsuka, Bunkyo-ku, Tokyo 112-8610, Japan

Abstract

Based on a new strategy of utilizing negative charges, a dibenzo[b,f]silepinyl dianion was synthesized and its hyperconjugative antiaromatic character is disclosed using NMR studies, large NICSzz values, and ACID plots.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC04434F

Reference44 articles.

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