Synthesis and properties of block copolymers composed of norbornene/higher α-olefin gradient segments using ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] catalyst system-Reference-Cited by-同舟云学术

Synthesis and properties of block copolymers composed of norbornene/higher α-olefin gradient segments using ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] catalyst system

Published:2021 Issue:2 Volume:12 Page:189-195
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Yuan Haobo¹²³⁴,Kida Takumitsu¹²³⁴,Tanaka Ryo¹²³⁴^ORCID,Cai Zhengguo⁵⁶⁷⁸⁹^ORCID,Nakayama Yuushou¹²³⁴^ORCID,Shiono Takeshi¹²³⁴^ORCID

Affiliation:

1. Graduate School of Advanced Science and Engineering

2. Hiroshima University

3. Higashi-Hiroshima 739-8527

4. Japan

5. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials

6. College of Materials Science and Engineering

7. Donghua University

8. Shanghai 201620

9. P.R. China

Abstract

A series of di- and triblock copolymers composed of gradient norbornene (NB)/α-olefin segments were synthesized by a (t-BuNSiMe₂Flu)TiMe₂-based catalyst and their physical and mechanical properties were investigated.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D0PY01370F

Reference35 articles.

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2. Recent Progress in the Vinylic Polymerization and Copolymerization of Norbornene Catalyzed by Transition Metal Catalysts

3. Recent progress in the chemical modification of syndiotactic polystyrene