Conversion-intercalation competing behaviour of halogen storage on graphite electrode from fluid ZnCl2/ZnBr2 hydrates

Author:

Xu Shiguan1,Shen Lin1,Wang Xiaoxu1,Gu Shaonan2,Sun Wei1,Huang Yuhao1ORCID

Affiliation:

1. Hainan Engineering Research Center of Tropical Ocean Advanced Optoelectronic Functional Materials, Key Laboratory of Laser Technology and Optoelectronic Functional Materials of Hainan Province, Key Laboratory of Functional Materials and Photoelectrochemistry of Haikou, College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China

2. Key Laboratory of Fine Chemicals in Universities of Shandong, Jinan Engineering Laboratory for Multi-scale Functional Materials, School of Chemistry and Chemical Engineering, Qilu University of Technology, Jinan 250353, P. R. China

Abstract

The macroscopic electrode reaction depends on both the ion-pair solvation state at the graphite–electrolyte interface and the subsequent reactant supply influenced by the electrode reaction rate.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hainan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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