Correlation between the surface electronic structure and CO-oxidation activity of Pt alloys

Author:

Abe Hideki12345,Yoshikawa Hideki123,Umezawa Naoto12345,Xu Ya123,Saravanan Govindachetty12367,Ramesh Gubbala V.123,Tanabe Toyokazu123,Kodiyath Rajesh123,Ueda Shigenori893,Sekido Nobuaki123,Yamabe-Mitarai Yoko123,Shimoda Masahiko123,Ohno Takahisa123,Matsumoto Futoshi101112133,Komatsu Takayuki1415163

Affiliation:

1. National Institute for Materials Science

2. Tsukuba

3. Japan

4. Precursory Research for Embryonic Science and Technology (PRESTO)

5. Japan Science and Technology Agency (JST)

6. CSIR-National Environmental Engineering Research Institute (CSIR-NEERI)

7. Environmental Materials Division

8. NIMS Beamline Station at SPring-8

9. Sayo

10. Department of Material and Life Chemistry

11. Faculty of Engineering

12. Kanagawa University

13. Kanagawa-ku

14. Department of Chemistry and Materials Science

15. Tokyo Institute of Technology

16. Meguro-ku

Abstract

The CO-oxidation activity of Pt and Pt alloys, Pt3T (T = Ti, Hf, Ta, Pt), shows a volcano-type dependence on the d-band center of the catalysts.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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