Unveiling two antiaromatic <i>s</i>-indacenodicarbazole isomers with tunable paratropicity-Reference-Cited by-同舟云学术

Unveiling two antiaromatic s-indacenodicarbazole isomers with tunable paratropicity

Published:2022 Issue:61 Volume:58 Page:8492-8495
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Saha Hemonta Kumar¹^ORCID,Mallick Dibyendu²^ORCID,Das Soumyajit¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, Punjab, 140001, India

2. Department of Chemistry, Presidency University, Kolkata, 700073, India

Abstract

Two formally antiaromatic s-indacenodicarbazole isomers were synthesized and characterized, to show that the curved isomer possesses a stronger s-indacene paratropicity than that of the linear isomer.

Funder

Science and Engineering Research Board

Indian Institute of Technology Kharagpur

Indian Institute of Science Education and Research Pune

Ministry of Electronics and Information technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02318K

Reference38 articles.

1. Indeno[1,2-b]fluorenes: Fully Conjugated Antiaromatic Analogues of Acenes

2. 6,12-Diarylindeno[1,2-b]fluorenes: Syntheses, Photophysics, and Ambipolar OFETs

3. Toward Tetraradicaloid: The Effect of Fusion Mode on Radical Character and Chemical Reactivity

4. s-Indacene: A Delocalized, Formally Antiaromatic 12 ? Electron System

5. Ring Currents and Magnetic Properties of s-Indacene, an Archetypal Paratropic, Non-Antiaromatic Molecule

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