Supramolecular catalysis in confined space: making the pyrogallol[4]arene capsule catalytically active in non-competitive solvent-Reference-Cited by-同舟云学术

Supramolecular catalysis in confined space: making the pyrogallol[4]arene capsule catalytically active in non-competitive solvent

Published:2022 Issue:9 Volume:9 Page:2453-2463
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

La Manna Pellegrino¹,Talotta Carmen¹^ORCID,Gaeta Carmine¹^ORCID,Cohen Yoram²,Slovak Sarit²,Rescifina Antonio³^ORCID,Sala Paolo Della¹^ORCID,De Rosa Margherita¹^ORCID,Soriente Annunziata¹,Neri Placido¹

Affiliation:

1. Laboratory of Supramolecular Chemistry, Dipartimento di Chimica e Biologia “A. Zambelli”, Università di Salerno, Via Giovanni Paolo II 132, I-84084 Fisciano (Salerno), Italy

2. School of Chemistry, The Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv, 69978 Tel Aviv, Israel

3. Dipartimento di Scienze del Farmaco e della Salute Università di Catania, Viale Andrea Doria 6, I-95125 Catania, Italy

Abstract

The confined space inside the hexameric pyrogallol[4]arene capsule (CP6) has been exploited for the catalysis of the 1,3-dipolar cycloaddition (1,3-DC) between the proline-based iminium derivative I and nitrone 3, in the presence of the non-competitive benzene solvent.

Funder

Università degli Studi di Salerno

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00172A

Reference57 articles.

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