A practical and effective method for the N–N bond cleavage of N-amino-heterocycles-Reference-Cited by-同舟云学术

A practical and effective method for the N–N bond cleavage of N-amino-heterocycles

Published:2019 Issue:19 Volume:6 Page:3408-3414
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Mari Giacomo¹²³⁴⁵^ORCID,Favi Gianfranco¹²³⁴⁵^ORCID,Santeusanio Stefania¹²³⁴⁵^ORCID,Mantellini Fabio¹²³⁴⁵^ORCID,De Crescentini Lucia¹²³⁴⁵^ORCID

Affiliation:

1. Department of Biomolecular Sciences

2. Section of Chemistry and Pharmaceutical Technologies

3. University of Urbino “Carlo Bo”

4. 61029 Urbino (PU)

5. Italy

Abstract

An innovative, robust, regioselective, metal- and oxidant-free method to cleave the N–N bond of N-amino heterocycles, promoted by 1,2-diaza-1,3-dienes is here presented. The process involves a Michael type addition/E1cb elimination sequence.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00895K

Reference63 articles.

1. .pi.-Bond strengths in the second and third periods

2. C. C. Marvin , in Comprehensive Organic Synthesis , ed. P. Knochel and G. Molander , Elsevier B. V. , Amsterdam , 2nd edn, 2014 , vol. 6 , pp. 34–99

3. S.-I. Murahashi and Y.Imada , in Asymmetric Synthesis , ed. M. Christmann and S. Brase , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim , 2nd edn, 2008 , pp. 42–47

4. Synthesis of secondary amines

5. Oxidative ring-opening of 3-aminoindazoles for the synthesis of 2-aminobenzoates

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