Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(iv) complexes-Reference-Cited by-同舟云学术

Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(iv) complexes

Published:2015 Issue:5 Volume:6 Page:2909-2921
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ye Shengfa¹²³,Xue Genqiang⁴⁵⁶⁷⁸,Krivokapic Itana¹²³,Petrenko Taras¹²³,Bill Eckhard¹²³,Que Jr Lawrence⁴⁵⁶⁷⁸,Neese Frank¹²³

Affiliation:

1. Max-Planck Institut für Chemische Energiekonversion

2. D-45470 Mülheim an der Ruhr

3. Germany

4. Department of Chemistry

5. Center for Metals in Biocatalysis

6. University of Minnesota

7. Minneapolis

8. USA

Abstract

The electronic structures of mononuclear and dinuclear iron(iv) complexes are studied using magnetic circular dichroism and wavefunction-based ab initio methods, and then correlated with their similar reactivities toward H- and O-atom transfer.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03268C

Reference131 articles.

1. Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes

2. Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates

3. Non-Heme Fe(IV)–Oxo Intermediates

4. Fe(II)/α-Ketoglutarate-Dependent Hydroxylases and Related Enzymes

5. Mechanism of Aromatic Amino Acid Hydroxylation

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