Local structure and NO adsorption/desorption property of Pd2+ cations at different paired Al sites in CHA zeolite

Author:

Yasumura Shunsaku1ORCID,Ueda Taihei1,Ide Hajime1,Otsubo Katsumasa2,Liu Chong3ORCID,Tsunoji Nao2ORCID,Toyao Takashi14ORCID,Maeno Zen1ORCID,Shimizu Ken-ichi14ORCID

Affiliation:

1. Institute for Catalysis, Hokkaido University, N-21, W-10, Sapporo 001-0021, Japan

2. Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan

3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

4. Elements Strategy Initiative for Catalysts and Batteries, Kyoto University, Katsura, Kyoto 615-8520, Japan

Abstract

The present study, based on a combination of theoretical and experimental techniques, shows that the NO adsorption/desorption properties over Pd-CHA can be tuned by controlling the Pd loading amount and the type of paired Al sites.

Funder

Core Research for Evolutional Science and Technology

Japan Society for the Promotion of Science

Hokkaido University

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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