Chemically driven superstructural ordering leading to giant unit cells in unconventional clathrates Cs8Zn18Sb28 and Cs8Cd18Sb28-Reference-Cited by-同舟云学术

Chemically driven superstructural ordering leading to giant unit cells in unconventional clathrates Cs8Zn18Sb28 and Cs8Cd18Sb28

Published:2020 Issue:37 Volume:11 Page:10255-10264
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Owens-Baird Bryan¹²³⁴⁵,Yox Philip¹²³⁴⁵^ORCID,Lee Shannon¹²³⁴⁵^ORCID,Carroll Xian B.¹⁶⁷⁴,Grass Wang Suyin⁸⁹¹⁰¹¹⁴^ORCID,Chen Yu-Sheng⁸⁹¹⁰¹¹⁴,Lebedev Oleg I.¹²¹³¹⁴¹⁵¹⁶,Kovnir Kirill¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Iowa State University

3. Ames

4. USA

5. Ames Laboratory

6. University of Tennessee

7. Knoxville

8. NSF's ChemMatCARS

9. Center for Advanced Radiation Source

10. The University of Chicago

11. Argonne

12. Laboratorie CRISMAT

13. UMR 6508

14. CNRS-ENICAEN

15. Caen 14050

16. France

Abstract

Giant clathrate supercell driven by ordering of Zn/Sb bonding in the framework and Cs-guest vacancies is found in unconventional clathrate Cs₈Zn₁₈Sb₂₈.

Funder

National Science Foundation

Basic Energy Sciences

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03846F

Reference43 articles.

1. Clathrate thermoelectrics