A rigid anionic Janus bis(NHC) – new opportunities in NHC chemistry

Author:

Naz Nabila Rauf123,Schnakenburg Gregor123,Kelemen Zsolt4567,Gál Dalma4567,Nyulászi László4567ORCID,Boeré René T.891011ORCID,Streubel Rainer123ORCID

Affiliation:

1. Institut für Anorganische Chemie der Rheinischen Friedrich-Wilhelms-Universität Bonn

2. 53121 Bonn

3. Germany

4. Department of Inorganic and Analytical Chemistry and MTA-BME Computation Driven Chemistry Research Group

5. Budapest University of Technology and Economics

6. 1111 Budapest

7. Hungary

8. Department of chemistry and biochemistry

9. University of Lethbridge

10. Lethbridge

11. Canada

Abstract

Formation of anionic ditopic N-heterocyclic dicarbene having two linking phosphorus centers – one neutral and one anionic is presented, along with a first glimpse on the coordination chemistry of bis(imidazolium) salts.

Funder

Rheinische Friedrich-Wilhelms-Universität Bonn

Alexander von Humboldt-Stiftung

Magyar Tudományos Akadémia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference28 articles.

1. N-Heterocyclic Carbenes in Synthesis , ed. S. P. Nolan , Wiley-VCH , Weinheim , 2006

2. S. D. Gonzalez , N-Heterocyclic, Carbenes: From Laboratory Curiosities To Efficient Synthetic Tools , Royal Society of Chemistry , Cambridge, U.K. , 2011

3. Heterocyclic Carbenes: Synthesis and Coordination Chemistry

4. N-Heterocyclic carbenes/imidazolium salts as substrates in catalysis: the catalytic 2-substitution and annulation of heterocyclic compounds

5. Chiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysis

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