Coupling of fluoroborylene ligands in manganese carbonyl chemistry to give a difluorodiborene ligand-Reference-Cited by-同舟云学术

Coupling of fluoroborylene ligands in manganese carbonyl chemistry to give a difluorodiborene ligand

Published:2019 Issue:21 Volume:43 Page:8220-8228
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Xu Liancai¹²³⁴,Li Qian-shu⁵⁶⁷⁴⁸,King R. Bruce⁵⁶⁷⁴⁹^ORCID

Affiliation:

1. Department of Material and Chemical Engineering

2. Zhengzhou University of Light Industry

3. Zhengzhou 450002

4. P. R. China

5. Center for Computational Quantum Chemistry

6. South China Normal University

7. Guangzhou 510631

8. Institute of Chemical Physics

9. Department of Chemistry and Center for Computational Chemistry

Abstract

A bridging difluorodiborene μ-B₂F₂ ligand has been observed in two of the three lowest energy Mn₂(BF)₂(CO)₇ structures as well as in the lowest energy Mn₂(BF)₂(CO)₆ structure.

Funder

National Natural Science Foundation of China

Zhengzhou University of Light Industry

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ01209E

Reference51 articles.

1. Boron-Fluorine Chemistry. I. Boron Monofluoride and Some Derivatives

2. Coordination and Activation of the BF Molecule

3. Chemistry of boron and silicon subhalides

4. Matrix infrared spectra and electronic structure calculations of the first actinide borylene: FBThF2

5. Calculations and Matrix Infrared Spectra of Terminal Borylene Complexes FBMF2

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