Syntheses, crystal structures and isomerization kinetics of a series of [Co(dtc)2{P(OMe)3 − nPhn}2]+(n = 0–2) complexes (dtc−= N,N-dimethyldithiocarbamate): role of σ-donicity, π-acidity, and cone angle of the P-ligands in the trans influence and trans effect
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2003/DT/B301712E
Reference41 articles.
1. Preparation and Properties of Cobalt(III)–1,2-Bis(dimethylphosphino)ethane (dmpe) Complexes of the [Co(L)(dmpe)2]n+Type
2. Preparation and Characterization of Cobalt(III)-Dimethyldithiocarbamato Complexes Containing R2P(CH2)nPR2(R=CH3, C6H5;n=1,2,3,4) and PR3(R=C2H5, C6H5). Crystal Structure of [Co{(CH3)2NCS2}{(CH3)2PCH2P(CH3)2}2](BF4)2
3. Preparation and Characterization of Cobalt(III) Complexes Containing 1,1′-Bis(diphenylphosphino)ferrocene (dppf) or 1,1′-Bis(dimethylphosphino)ferrocene (dmpf) as a Bidentate Ligand, and Molecular Structures of [Co(acac)2(dmpf)]B(C6H5)4and [Co(dtc)2(dmpf)]B(C6H5)4(acac = 2,4-pentanedionate ion, dtc = dimethyldithiocarbamate ion)
4. Preparation and Characterization of Co(III)-Dimethyldithiocarbamato Complexes Containing 1,2-Bis(dimethoxyphosphino)ethane. Molecular Structures of [Co{(CH3)2NC(S)S}{R2P(CH2)2PR2}2] (BF4)2(R = CH3O and CH3)
5. Preparation and Characterization of Dithiocarbamatocobalt(III) Complexes Containing Phosphites, and Molecular Structures ofcis-[Co{(CH3)2NCS2}2{P(OCH2)3CC2H5}2]BF4and [Co(CH2CH2CH2CH2CH2NCS2){P(OCH3)3}4](BF4)2
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